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Four-stroke engine cycle produces hydrogen from methane and captures CO2

When is an internal combustion engine not an internal combustion engine? When it's been transformed into a modular reforming reactor that could make hydrogen available to power fuel cells wherever there's a natural gas supply available. By adding a catalyst, a hydrogen separating membrane and carbon dioxide sorbent to the century-old four-stroke engine cycle, researchers have demonstrated a laboratory-scale hydrogen reforming system that produces the green fuel at relatively low temperature in a process that can be scaled up or down to meet specific needs. The process could provide hydrogen at the point of use for residential fuel cells or neighborhood power plants, electricity and power production in natural-gas powered vehicles, fueling of municipal buses or other hydrogen-based vehicles, and supplementing intermittent renewable energy sources such as photovoltaics. Known as the CO2/H2 Active Membrane Piston (CHAMP) reactor, the device operates at temperatures much lower than conventional steam reforming processes, consumes substantially less water and could also operate on other fuels such as methanol or bio-derived feedstock. It also captures and concentrates carbon dioxide emissions, a by-product that now lacks a secondary use—though that could change in the future. Unlike conventional engines that run at thousands of revolutions per minute, the reactor operates at only a few cycles per minute—or more slowly—depending on the reactor scale and required rate of hydrogen production. And there are no spark plugs because there's no fuel combusted. "We already have a nationwide natural gas distribution infrastructure, so it's much better to produce hydrogen at the point of use rather than trying to distribute it," said Andrei Fedorov, a Georgia Institute of Technology professor who's been working on CHAMP since 2008. "Our technology could produce this fuel of choice wherever natural gas is available, which could resolve one of the major challenges with the hydrogen economy."

Read More: Phys.Org

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